Volgin had incredible strength which made him a deadly foe in battle, his blows being powerful enough to send an opponent flying as well as vomit. In addition, he was capable of not only lifting, but also wielding with ease, a davy crockett launcher by hand (Davy Crocketts weigh about 300 kilograms combined with the launcher and the Davy Crockett itself, and personnel using it generally utilize a tripod). He was also skilled with guns: He used his Makarov sidearm to shoot Sokolov in the kneecaps after deducing Major Raikov was Naked Snake in disguise. Colonel Volgin then turned the Makarov on Snake but the gun was disarmed from him with Snake's quick CQC skills. It was attempted to be used on Snake again once The Boss overpowered him, and The Boss did a similar disarming maneuver to render him bare-handed.
Volgin's body possessed a physical anomaly that allowed him to generate 10 million volts of electricity at will, and he specialized in electric shock attacks. To protect himself from being injured by this exceedingly high voltage, having caused the numerous scars to his face, Volgin wore a rubber suit during combat. While wearing it, he could generate his maximum level of voltage, using it to enhance his strength to superhuman levels. He demonstrated this by punching through the solid metal of the Shagohod's armor, which even the RPG-7's shaped-charge warhead was unable to penetrate directly. Volgin was also known to perform an attack that did damage on three levels; to hold four bullets between his knuckles, punch a person, and drop the bullet casings in an intimidating manner. It worked three-fold, a punch, igniting the bullet's gunpowder for a "gunshot" effect, and using the metal of the bullets to conduct an electricity shock on the opponent. He first showcased this ability on a concrete wall after learning from The Boss that The Pain had been killed by Naked Snake.